Google automatically sets you up with Picasa, YouTube, iGoogle, etc. You don't have to use the accounts they set up. I have my own YouTube account, not associated with Google. I could link it if I chose, but I don't. As far as I know, you cannot sever one of the products from your Google package permanently.
If you really wanted to use Google and a non-Google YouTube account at the same time, maybe you could open up Explorer for the YouTube account?
You can set Firefox to automatically remove all cookies, browsing history, and passwords when you close it. When I'm done on my computer, I close Firefox and the next time it's opened, everything is at a log in screen.
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"First they ignore you, then they ridicule you, then they fight you, then you win."
- Mahatma Gandhi
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