If you've been to Rome and Venice I'd go to Tuscany (region) and especially Siena (city). It's a mediaevil
Any Italian city that has a guide book is worth at least a 5 day tour, and many will reward you if you spend more time there. Try not to think in times if sights to "do". Wherever you go, get a walking guide - Brit & US students in Italy make their living/ spending money on tours and they are very good value
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