Nearest thing to a horned carnivore I can think of is the norwhal, and that's more a tusk. There are plenty of protectively clad carnivores, from the croc's scutes to a lion's mane.
Arthropods are a whole 'nother game, and perhaps should be left to another topic. There aren't any vegetarian spiders, if I understand rightly.
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Wanna stop school shootings? End Gun-Free Zones, of course.
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